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Lead Dioxide

Lead Dioxide

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Description
Assay, percent: 97
Clarity: Pass test
Nitrate(HNO3), percent: 0.1
Chloride(Cl), percent: 0.005
Carbonate(CO3), percent: 0.0003
Nitrogen(N), percent: 0.01
H2S non-precipitation, percent: 0.5
Cupric(Cu), percent: 0.001

Property:
Lead dioxide is a strong oxidizing agent which is used in the manufacture of matches, pyrotechnics, dyes and other chemicals. It also has several important applications in electrochemistry, in particular as a component of lead acid batteries.

Usage:
1. As a strong oxidizing agent, lead dioxide is widely used in the production of matches, pyrotechnics, dyes and other chemicals. Its another large-scale application is in the curing of sulfide polymers and in high-voltage lightning arresters.

2. Lead dioxide is used as anode material in electrochemistry. Beta-PbO2 is more attractive for this purpose than the alpha form because it has relatively low resistivity, good corrosion resistance even in low-pH medium, and a high overvoltage for the evolution of oxygen in sulfuric acid and nitric acid based electrolytes. Lead dioxide can also withstand chlorine evolution in hydrochloric acid. 3. Lead dioxide anodes are inexpensive and were once used instead of conventional platinum and graphite electrodes for regenerating potassium dichromate. They were also applied as oxygen anodes for electroplating copper and zinc in sulfate baths. In organic synthesis, lead dioxide anodes were applied for the production of glyoxylic acid from oxalic acid in a sulfuric acid electrolyte.

3. The most important use of lead dioxide is as the cathode of lead acid batteries. Its utility arises from the anomalous metallic conductivity of PbO2. The lead acid battery stores and releases energy by shifting the equilibrium (a comproportionation) between metallic lead, lead dioxide, and lead(II) salts in sulfuric acid.
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Lead Dioxide
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